The Dangerous Substances and Explosive Atmospheres Regulations 2002
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The Secretary of State in exercise of the powers conferred on him by sections 15(1), (2), (3)(a) and (5), 80(1) and 82(3)(a) of, and paragraphs 1(1), (2) and (4), 6, 9, 11, 14, 16, 18(b) and 20 of Schedule 3 to, the Health and Safety at Work etc. Act 1974[1] ("the 1974 Act") and of all other powers enabling him in that behalf and for the purpose of giving effect without modifications to proposals submitted to him by the Health and Safety Commission under section 11(2)(d) of the 1974 Act after the carrying out by the said Commission of consultations in accordance with section 50(3) of that Act, hereby makes the following Regulations: - Citation and commencement 1. These Regulations may be cited as the Dangerous Substances and Explosive Atmospheres Regulations 2002 and shall come into force -
(b) as respects regulations 15(2) and 16(2) on 5th May 2003; and (c) as respects regulations 5(4)(c), 7, 11 and 17(1) to (3) on 30th June 2003. Interpretation
(b) a substance or preparation which because of its physico-chemical or chemical properties and the way it is used or is present at the workplace creates a risk, not being a substance or preparation falling within subparagraph (a) above; or (c) any dust, whether in the form of solid particles or fibrous materials or otherwise, which can form an explosive mixture with air or an explosive atmosphere, not being a substance or preparation falling within subparagraphs (a) or (b) above;
(b) any room, lobby, corridor, staircase, road or other place -
(ii) where facilities are provided for use in connection with that place of work, other than a public road;
and
(b) connecting devices, (c) control and protection systems, (d) engineering controls and solutions, (e) equipment, (f) materials, (g) machinery, (h) plant, (i) protective systems, and (j) warning and other communication systems. Application
(b) the reference to the normal ship-board activities of a ship's crew includes -
(ii) the repair of a ship save repair when carried out in dry dock. (2) Regulations 5(4)(c), 7 and 11 shall not
apply to -
(b) the use of gas appliances burning gaseous fuel (that is to say, any fuel which is in a gaseous state at a temperature of 15°C under a pressure of 1 bar) which -
(ii) have, where applicable, a normal water temperature not exceeding 105°C including forced draught burners and heating bodies to be equipped
with such burners but not including an appliance specifically designed
for use in an industrial process carried out on industrial
premises; (3) Regulations 5(2)(f), (g), (h) and (i),
6(4)(d), 6(5)(b) and (e) and 8(1)(d) and (e) and the requirements of
paragraphs 5 and 6 of Schedule 1 shall not apply to any activity at an
offshore installation carried out for the purposes of the offshore
installation.
(b) the duties of the employer under regulations 8 and 9 (which relate, respectively, to dealing with accidents and to provision of information, instruction and training) shall not extend to persons who are not his employees, unless those persons are at the workplace where the work is being carried on and subject to the following, namely, that, in relation to the application of regulation 9 to such persons, regulation 9 shall apply to the extent that is required by the nature and the degree of the risk. (2) These Regulations shall apply to a
self-employed person as they apply to an employer and an employee and as
if that self-employed person were both an employer and
employee.
(b) information on safety provided by the supplier, including information contained in any relevant safety data sheet; (c) the circumstances of the work including -
(ii) the amount of the substance involved; (iii) where the work will involve more than one dangerous substance, the risk presented by such substances in combination; and (iv) the arrangements for the safe handling, storage and transport of dangerous substances and of waste containing dangerous substances; (d) activities, such as maintenance, where there is the potential for
a high level of risk; (3) The risk assessment shall be reviewed by
the employer regularly so as to keep it up to date and particularly
if -
(b) there has been a significant change in the matters to which the risk assessment relates including when the workplace, work processes, or organisation of the work undergoes significant changes, extensions or conversions; and where, as a result of the review, changes to the risk assessment
are required, those changes shall be
made.
(b) sufficient information to show that the workplace and work processes are designed, operated and maintained with due regard for safety and that, in accordance with the Provision and Use of Work Equipment Regulations 1998[13], adequate arrangements have been made for the safe use of work equipment; and (c) where an explosive atmosphere may occur at the workplace and subject to the transitional provisions in regulation 17(1) to (3), sufficient information to show -
(ii) equipment which is required for, or helps to ensure, the safe operation of equipment located in places classified as hazardous pursuant to regulation 7(1); (iii) that any verification of overall explosion safety required by regulation 7(4) has been carried out; and (iv) the aim of any co-ordination required by regulation 11 and the measures and procedures for implementing it. (5) No new work activity involving a dangerous
substance shall commence unless -
(b) the measures required by these Regulations have been implemented. Elimination or reduction of risks from dangerous
substances
(b) to mitigate the detrimental effects of a fire or explosion or the other harmful physical effects arising from dangerous substances, including the measures specified in paragraph (5). (4) The following measures are, in order of
priority, those specified for the purposes of paragraph
(3)(a) -
(b) the avoidance or minimising of the release of a dangerous substance; (c) the control of the release of a dangerous substance at source; (d) the prevention of the formation of an explosive atmosphere, including the application of appropriate ventilation; (e) ensuring that any release of a dangerous substance which may give rise to risk is suitably collected, safely contained, removed to a safe place, or otherwise rendered safe, as appropriate; (f) the avoidance of -
(ii) adverse conditions which could cause dangerous substances to give rise to harmful physical effects; and (g) the segregation of incompatible dangerous
substances. (5) The following measures are those specified
for the purposes of paragraph (3)(b) -
(b) the avoidance of the propagation of fires or explosions; (c) the provision of explosion pressure relief arrangements; (d) the provision of explosion suppression equipment; (e) the provision of plant which is constructed so as to withstand the pressure likely to be produced by an explosion; and (f) the provision of suitable personal protective equipment. (6) The employer shall arrange for the safe
handling, storage and transport of dangerous substances and waste
containing dangerous substances.
(b) information on emergency arrangements, including -
(ii) specific hazards likely to arise at the time of an accident, incident or emergency, is available; (2) Subject to paragraph (4), the employer
shall ensure that information on the matters referred to in paragraph
(1)(a), (c) to (e) and the information required by paragraph 1(b)
is -
(b) displayed at the workplace, unless the results of the risk assessment make this unnecessary. (3) Subject to paragraph (4), in the event of
an accident, incident or emergency related to the presence of a dangerous
substance at the workplace, the employer shall ensure
that -
(ii) restore the situation to normal, and (iii) inform those of his employees who may be affected; and (b) only those persons who are essential for the carrying out of
repairs and other necessary work are permitted in the affected area and
they are provided with -
(ii) any necessary specialised safety equipment and plant, which shall be used until the situation is restored to
normal. (4) Paragraphs (1) to (3) shall not apply
where -
(b) the measures taken by the employer to comply with his duty under regulation 6(1) are sufficient to control that risk. Information, instruction and
training
(b) the details of any such substance including -
(ii) access to any relevant safety data sheet; and (iii) legislative provisions which concern the hazardous properties of the substance; and (2) The information, instruction and training
required by paragraph (1) shall be -
(b) provided in a manner appropriate to the risk assessment. Identification of hazardous contents of containers and
pipes
(b) any requirements imposed by or under any enactments which apply to the case, it is satisfied that the health and safety of persons who are likely to
be affected by the exemption will not be prejudiced in consequence of it
and that the exemption will be compatible with the requirements of the
Directives.
(b) "visiting force" has the same meaning as it does for the purposes of any provision of Part 1 of the Visiting Forces Act 1952[17]; and (c) "headquarters" means a headquarters for the time being specified in Schedule 2 to the Visiting Forces and International Headquarters (Application of Law) Order 1999[18]. (2) The Secretary of State for Defence may, in
the interests of national security, by a certificate in writing,
exempt -
(b) any visiting force, (c) any member of a visiting force working in or attached to a headquarters, or (d) any person engaged in work involving dangerous substances, if that person is under the direct supervision of a representative of the Secretary of State for Defence, from all or any of the requirements or prohibitions imposed by these
Regulations and any such exemption may be granted subject to conditions
and to a limit of time and may be revoked at any time by a certificate in
writing, except that, where any such exemption is granted, suitable
arrangements shall be made for the assessment of the risk to safety
created by the work involving dangerous substances and for adequately
controlling the risk to persons to whom the exemption
relates.
(b) which is used for the first time after 30th June 2003 shall comply with the requirements of regulations 7 and 11 from the date that it is first used and the employer's duties under those regulations in respect of such a workplace shall apply accordingly. (3) If, after 30th June 2003, any modification,
extension or restructuring is undertaken in workplaces containing places
where explosive atmospheres may occur, the employer shall take the
necessary steps to ensure that the modification, extension or
restructuring complies with the requirements of regulations 7 and 11 and
the employer's duties under those regulations and in respect of such a
modification, extension or restructuring shall apply
accordingly. 1. The following measures are those specified for the purposes of regulation 6(8). 2. Ensuring that the workplace is designed, constructed and maintained so as to reduce risk. 3. Designing, constructing, assembling, installing, providing and using suitable work processes so as to reduce risk. 4. Maintaining work processes in an efficient state, in efficient working order and in good repair. 5. Ensuring that equipment and protective systems meet the following requirements -
(b) means for manual override must be possible, operated by employees competent to do so, for shutting down equipment and protective systems incorporated within automatic processes which deviate from the intended operating conditions, provided that the provision or use of such means does not compromise safety; (c) on operation of emergency shutdown, accumulated energy must be dissipated as quickly and as safely as possible or isolated so that it no longer constitutes a hazard; and (d) necessary measures must be taken to prevent confusion between connecting devices. 6. The application of appropriate
systems of work including -
(b) a system of permits to work with such permits being issued by a person with responsibility for this function prior to the commencement of the work concerned, where the work is carried out in hazardous places or involves hazardous
activities. 1. Places where explosive atmospheres may occur A place in which an explosive atmosphere may occur in such quantities as to require special precautions to protect the health and safety of the workers concerned is deemed to be hazardous within the meaning of these Regulations. A place in which an explosive atmosphere is not expected to occur in such quantities as to require special precautions is deemed to be non-hazardous within the meaning of these Regulations. 2. Classification of hazardous places Hazardous places are classified in terms of zones on the basis of the frequency and duration of the occurrence of an explosive atmosphere. Zone 0 A place in which an explosive atmosphere consisting of a mixture with air of dangerous substances in the form of gas, vapour or mist is present continuously or for long periods or frequently. Zone 1 A place in which an explosive atmosphere consisting of a mixture with air of dangerous substances in the form of gas, vapour or mist is likely to occur in normal operation occasionally. Zone 2 A place in which an explosive atmosphere consisting of a mixture with air of dangerous substances in the form of gas, vapour or mist is not likely to occur in normal operation but, if it does occur, will persist for a short period only. Zone 20 A place in which an explosive atmosphere in the form of a cloud of combustible dust in air is present continuously, or for long periods or frequently. Zone 21 A place in which an explosive atmosphere in the form of a cloud of combustible dust in air is likely to occur in normal operation occasionally. Zone 22 A place in which an explosive atmosphere in the form of a cloud of combustible dust in air is not likely to occur in normal operation but, if it does occur, will persist for a short period only. Notes: 1. Layers, deposits and heaps of combustible dust must be considered as any other source which can form an explosive atmosphere. 2. "Normal operation" means the situation when installations are used within their design parameters. 1. Equipment and protective systems for all places in which explosive atmospheres may occur must be selected on the basis of the requirements set out in the Equipment and Protective Systems Intended for Use in Potentially Explosive Atmospheres Regulations 1996[21] unless the risk assessment finds otherwise. 2. In particular, the following categories of equipment must be used in the zones indicated, provided they are suitable for gases, vapours, mists, dusts or mists and dusts, as appropriate: - in zone 0 or zone 20, category 1 equipment, - in zone 1 or zone 21, category 1 or 2 equipment, - in zone 2 or zone 22, category 1, 2 or 3 equipment. 3. For the purposes of this Schedule and regulations 7(2) and 17(1) -
(b) "protective systems" means devices other than components of equipment which are intended to halt incipient explosions immediately or limit the effective range of an explosion or both, as the case may be, and which systems are separately placed on the market for use as autonomous systems; (c) "devices" means safety devices, controlling devices and regulating devices intended for use outside potentially explosive atmospheres but required for or contributing to the safe functioning of equipment and protective systems with respect to the risks of explosion; (d) "component" means any item essential to the safe functioning of equipment and protective systems but with no autonomous function; and (e) "potentially explosive atmosphere" means an atmosphere which could become explosive due to local and operational conditions.
![]() Distinctive features:
(b) black letters on a yellow background with black edging (the yellow part to take up at least 50% of the area of the sign).
The Classification and Labelling of Explosives Regulations 1983 (S.I. 1983/1140). The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 (S.I. 2002/1689). The Health and Safety (Safety Signs and Signals) Regulations 1996 (S.I. 1996/341). The Radioactive Material (Road Transport) (Great Britain) Regulations 1996 (S.I. 1996/1350). The Carriage of Dangerous Goods by Rail Regulations 1996 (S.I. 1996/2089). The Packaging, Labelling and Carriage of Radioactive Material by Rail Regulations 1996 (S.I. 1996/2090). The Carriage of Dangerous Goods (Classification, Packaging and Labelling) and Use of Transportable Pressure Receptacles Regulations 1996 (S.I. 1996/2092). The Carriage of Explosives by Road Regulations 1996 (S.I. 1996/2093). The Carriage of Dangerous Goods by Road Regulations 1996 (S.I. 1996/2095). The Good Laboratory Practice Regulations 1997 (S.I. 1997/654). 1. In section 2 of the Celluloid and Cinematograph Film Act 1922[22] (purposes to which Act applies), after paragraph (iii) of the proviso insert
2. - (1) The Petroleum
(Consolidation) Act 1928[24]
is amended as follows.
(b) carriage to which the Carriage of Dangerous Goods by Road Regulations 1996[25] apply.". (5) In section 23
(interpretation) -
(6) Re-number section 25A[28]
(places to which Act does not apply) as subsection (1) and insert at the
end
(2) For the purposes of subsection (1)(c),
any part of a workplace where petroleum-spirit is kept other than for
dispensing is not to be regarded as used, or intended for use, for
dispensing petroleum-spirit.". 3. - (1) The
Petroleum-Spirit (Motor Vehicles etc.) Regulations 1929[29]
are amended as follows.
(b) to prevent the leakage of any liquid or vapour therefrom. (2) Where the vessel in which the
petroleum-spirit is to be kept is a fuel tank for an internal combustion
engine, the requirement in paragraph (1) that the vessel be made of
metal shall not apply.". (3) In regulation 7, insert at the beginning of
paragraph (1) "Subject to paragraph (3) below," and after paragraph (2)
insert -
(4) In regulation 15A (disapplication), omit
"and" at the end of paragraph (a) and insert after paragraph
(b) -
4. The Petroleum (Liquid Methane) Order
1957[30]
is amended by the insertion at the end of the Schedule (provisions of the
Petroleum (Consolidation) Act 1928 not applied to liquid methane), of
"Section 25A(1)(c) and (2)".
(3) In regulation 2(1) (enforcing
authorities) -
(b) omit subparagraph (a)(i), (iii) and (iv); (c) insert after subparagraph (c) -
(ii) in so far as they apply to any activity relating to fuelling motor vehicles, ships and aircraft with petroleum-spirit at a non-retail petroleum filling station, including any petroleum-spirit dispenser, other apparatus or storage tank for storing petroleum-spirit used thereat in connection with that fuelling."; and (d) after paragraph (3), insert -
(b) any establishment to which the Control of Major Accident Hazards Regulations 1999[34] apply by virtue of regulation 3 of those Regulations; (c) any site in respect of which notification of an activity is required pursuant to regulation 3 of the Notification of Installations Handling Hazardous Substances Regulations 1982[35]; and (d) any activity at a retail or a non-retail petroleum filling station connected with repairing motor vehicles, ships or aircraft or retailing goods other than, in relation to a retail petroleum filling station, vehicle fuel and, in relation to a non-retail petroleum filling station, petroleum-spirit.". 6. - (1) The
Petroleum-Spirit (Plastic Containers) Regulations 1982[36]
are amended as follows.
7. The Dangerous Substances in Harbour
Areas Regulations 1987[37]
are amended by the omission of "the Petroleum (Carbide of Calcium) Order
1929" in regulation 29 (application of Part VIII - storage of
dangerous substances). 9. - (1) The Fire Certificates (Special Premises) Regulations 1976[39] are amended as follows. (2) In paragraph 25 of Part III of Schedule 1 (premises for which a fire certificate is required), for the definition of "highly flammable liquid" substitute -
(b) when tested at 50°C (within an accuracy of -0 +5°C) using the procedure referred to in Appendix B to the "Approved Requirements and test methods for the classification and packaging of dangerous goods for carriage"[40] with a heating time of 60 seconds supports combustion, and for these purposes -
(ii) "the Directive" means Commission Directive 92/69 EEC[41] adapting to technical progress for the seventeenth time Council Directive 67/548/EEC[42] on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances; and (iii) "liquefied flammable gas" means any substance which at a temperature of 20°C and a pressure of 760 millimetres of mercury would be a flammable gas, but which is in liquid form as a result of the application of pressure refrigeration or both.". 10. The Carriage of Dangerous Goods by
Road Regulations 1996[43]
are amended by the substitution for regulation 20 (unloading of petrol at
petroleum filling stations and certain other premises licensed for the
keeping of petrol) of -
20. - (1) Neither the fuel tank for an internal combustion engine nor a portable container shall be filled or replenished with petrol direct from a road tanker conveying petrol in such circumstances that these Regulations apply to that conveyance. (2) Except in relation to Her Majesty's Forces, the enforcing authority for these Regulations and for sections 2 to 4 and section 7 and 8 of the Health and Safety at Work etc. Act 1974 in respect of such filling or replenishing with petrol as is referred to in paragraph (1) at any premises for which a petroleum-spirit licence authorising the keeping of petrol is required under the 1928 Act, shall be the petroleum licensing authority, even if the relevant tanker is on a road at the time of that filling or replenishing. (3) In this regulation -
(b) "the Directive" means Commission Directive 92/69 EEC adapting to technical progress for the seventeenth time Council Directive 67/548/EEC on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances; (c) "Her Majesty's Forces" means any of the naval, military or air forces of the Crown, whether raised inside or outside the United Kingdom and whether any such force is a regular, auxiliary or reserve force, and includes any civilian employed by those forces; (d) "petrol" means petroleum-spirit intended for use as a fuel for an internal combustion engine; (e) "the petroleum licensing authority" means the local authority empowered to grant petroleum-spirit licences under the 1928 Act for the premises concerned; (f) "petroleum-spirit" means petroleum which, when tested in accordance with Part A.9. of the Annex to the Directive has a flash point (as defined in that Part) of less than 21°C; and (g) "petroleum-spirit licence" means a licence authorising the keeping of petroleum-spirit granted by a local authority empowered under the 1928 Act to grant such a licence or by the Secretary of State or by the Health and Safety Executive.".
(This note is not part of the Regulations) 1. These Regulations impose requirements for the purpose of eliminating or reducing risks to safety from fire, explosion or other events arising from the hazardous properties of a "dangerous substance" in connection with work. "Dangerous substance" is defined by regulation 2(1) to mean:
(b) a substance or preparation which because of its physico-chemical or chemical properties and the way it is used or is present at the workplace creates a risk, not being a substance or preparation falling within subparagraph (a) above; or (c) any dust, whether in the form of solid particles or fibrous materials or otherwise, which can form an explosive mixture with air or an explosive atmosphere, not being a substance or preparation falling within subparagraphs (a) or (b) above. 2. The Regulations implement, as
regards Great Britain, Council Directive 98/24/EC (OJ No. L 131, 5.9.98,
p.11) on the protection of the health and safety of workers from the risks
related to chemical agents at work, so far as that Directive relates to
safety, and Council Directive 99/92/EC (OJ No. L 23, 28.1.00, p.57) on
minimum requirements for improving the safety and health protection of
workers potentially at risk from explosive atmospheres. Both of these
Directives are individual Directives within the meaning of Article 16(1)
of Council Directive 89/391/EC. Notes: [1] 1974 c. 37; section 15(1), 50(3) and 52 were amended by the Employment Protection Act 1975 (c. 71), Schedule 15, paragraphs 6, 16(3) and 17 respectively; section 51A was added and section 52 was amended by the Police (Health and Safety) Act 1997 (c. 42), sections 1 and 2 respectively; the general purposes of Part 1 of the 1974 Act were extended by the Offshore Safety Act 1992 (c. 15), section 1(1).back [5] OJ No. L348, 28.11.92, p. 9.back [9] 1954 c. 70, extended by the Mines and Quarries (Tips) Act 1969 (c. 10) and the Mines Management Act 1971 (c. 20); relevant amending instruments are S.I. 1974/2013, 1976/2063 and 1993/1897.back [12] OJ No. L 23, 28.1.00, p. 57.back [13] S.I. 1998/2306, amended by S.I. 1999/860 and 1999/2001.back [15] OJ No. L 131, 5.9.98, p. 11.back [16] OJ No. L 23, 28.1.00, p. 57.back [17] 1952 c. 67 (15 & 16 Geo 6 & 1 Eliz 2).back [19] 1928 c. 32. Section 2(1) is amended by the Local Government Act 1972 (c. 70) section 251 and Schedule 29, Part II paragraph 32, by the Local Government Act 1985 (c. 51) section 37 and Schedule II paragraph 4, by the Local Government (Wales) Act 1994 (c. 19) section 22(3) and Schedule 9 paragraph 2 and by S.I. 1995/2923.back [20] OJ No. L 23, 28.1.00, p. 57.back [21] S.I. 1996/192, amended by S.I. 2001/3766.back [22] 1922 c. 35. Section 2 is amended by the Cinemas Act 1985 (c. 13), section 24(1) and Schedule 2, paragraph 1 and S.I. 1992/1811.back [23] S.I. 1997/1840, amended by S.I. 1999/1877 and 1999/3242.back [24] 1928 c. 32. Section 2(1) is amended by the Local Government Act 1972 (c. 70) section 251 and Schedule 29, Part II paragraph 32, by the Local Government Act 1985 (c. 51) section 37 and Schedule II paragraph 4 and by the Local Government (Wales) Act 1994 (c. 19) section 22(3) and Schedule 9 paragraph 2; section 18 is amended by S.I. 1974/1942, 1986/1951 and 1992/743; section 23 is amended by the Statute Law (Repeals) Act 1993 (c. 50) and by S.I. 1974/1942, 1992/1811, 1993/1746 and 1994/3247; section 25A is inserted by S.I. 1999/743.back [25] S.I. 1996/2095, amended by S.I. 1998/2885, 1999/257, 1999/303 and 2001/1426.back [26] OJ No. L383, 29.12.92, p. 113.back [27] OJ No. 196, 16.8.67, p. 1.back [28] Section 25A was inserted by S.I. 1999/743.back [29] S.I. 1929/952, amended by S.I. 1979/427, 1982/630, 1992/1811 and 1999/743; the last mentioned instrument inserted regulation 15A(a) and (b).back [31] S.I. 1979/427, amended by S.I. 1981/1059, 1982/630 and 1986/1951.back [32] OJ No. L383, 29.12.92, p. 113.back [33] OJ No. 196, 16.8.67, p. 1.back [34] S.I. 1999/743, amended by the Greater London Authority Act 1999 (c. 29), section 328(7), and S.I. 1999/2597.back [35] S.I. 1982/1357, amended by S.I. 1996/825.back [36] S.I. 1982/630, amended by S.I. 1999/743.back [37] S.I. 1987/37, amended by S.I. 1993/1746, 1994/669, 1994/3247, 1996/2092, 1996/2095, 1997/2367, 1998/2885 and 1999/2029.back [38] S.I. 1997/1840, amended by S.I. 1999/1877 and 1999/3242.back [39] S.I. 1976/2003, amended by S.I. 1985/1333, 1987/37 and 1992/1811.back [41] OJ No. L383, 29.12.92, p. 113.back [42] OJ No. 196, 16.8.67, p. 1.back [43] S.I. 1996/2095, amended by S.I. 1998/2885, 1999/257, 1999/303 and 2001/1426.back [45] Regulations 48 to 52 and 54 were revoked by S.I. 1997/1713, regulation 9(2) and the Schedule, save insofar as they applied to the matters referred to in regulation 2(a) to (c) of S.I. 1997/1713.back
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